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A convenient source of the 2-phenylethynethiolate anion upon reaction with potassium tert-butoxide: Can. J. Chem., 46, 1057 (1968), which forms thiocarbonyls with CS2 and alkynesulfides with alkyl halides: Molecules, 1, 190 (1996). Undergoes flash vacuum pyrolysis at 500oC to give the unstable phenylthioketene: J. Heterocycl. Chem., 12, 605 (1975)./n
Gefahrenhinweise (EU): H302-H315-H319-H335
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.