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624-65-7 - Propargyl chloride, 70% w/w soln. in toluene - 3-Chloro-1-propyne - L20416 - Alfa Aesar

L20416 Propargyl chloride, 70% w/w soln. in toluene

CAS-Nummer
624-65-7
Synonyme
3-Chloro-1-propyne

Größe Preis ($) Menge Verfügbarkeit
25g 33,70
100g 97,70
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Propargyl chloride, 70% w/w soln. in toluene

MDL
MFCD00000980
EINECS
210-856-9

Chemische Eigenschaften

Formel
C3H3Cl
Molmasse
74.51
Schmelzpunkt
<-50°
Siedepunkt
60-63°
Flammpunkt
-15°(-5°F)
Dichte
0.990
Brechungsindex
1.456
Löslichkeit
Not miscible or difficult to mix with water.

Anwendungen

Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols. Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.

Bemerkungen

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Literaturverweise

Lyudmila A. Grischenko; Lidiya N. Parshina; Lyudmila V. Kanitskaya; Lyudmila I. Larina; Lyubov N. Novikova; Boris A. Trofimov. Propargylation of arabinogalactan with propargyl halides—a facile route to new functionalized biopolymers. Carbohydrate Research. 2013, 376 7-14.

Nakajima M, et al. Selective synthesis of optically active allenic and homopropargylic alcohols from propargyl chloride. Tetrahedron Asymmetry. 2002, 12 (22), 2449-52.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H301-H311-H331-H336-H304-H361-H373-H314

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage.

Sicherheitshinweise: P210-P260-P201-P301+P310-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,7810
Beilstein
506005
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2903.29
TSCA
Yes

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