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10019 Cesium fluoride, 99.9% (metals basis)

CAS Number

Stock No. Size Price ($) Quantity Availability
10019-88 2.5g 19.20
10019-14 25g 91.90
10019-22 100g 149.00
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Cesium fluoride, 99.9% (metals basis)


Chemical Properties

Formula Weight
Melting point
Boiling Point
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Soluble in water. Insoluble in dioxane and pyridine.


Used for desilylation reactions in organic synthesis. Useful base in organic chemistry, due to its low nucleophilicity. Owing to its high ionic character, it is a very reactive source of fluoride ion in organic synthesis. Reagent of choice when reactive "naked" fluoride is required. Effective catalyst in promoting Knoevenegal condensation. Single crystals of CsF are useful as the windows of cells for infrared spectroscopy.


Cesium fluoride is hygroscopic. The adsorbed moisture can be removed by heating and drying under vacuum. Contact with acid should be avoided to prevent the formation of HF.

Literature References

Khana, K. M.; Hayata, S.; Zia-Ullaha; Atta-ur-Rahmana; Iqbal Choudharya, I. M.; Maharvia, G. M.; Baye, E. An Alternative Method for the Synthesis of γ-Lactones by Using Cesium Fluoride-Celite/Acetonitrile Combination. Synth. Commun. 2003, 33 (19), 3435-3453.

Mee, S. P. H.; Lee, V.; Baldwin, J. E. Stille Coupling Made Easier - The Synergic Effect of Copper(I) Salts and the Fluoride Ion. Angew. Chem. Int. Ed. 2004, 43, 1132-1136.

Reinhard, M.; Hanisch, J.; Zhang, Z.; Ahlswede, E.; Colsmann, A.; Lemmer, U. Inverted organic solar cells comprising a solution-processed cesium fluoride interlayer. Appl. Phys. Lett. 2011, 98, 053303.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H315-H318-H331-H361

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye damage. Toxic if inhaled. Suspected of damaging fertility or the unborn child.

Precautionary Statements: P201-P202-P261-P264b-P270-P271-P281-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P310-P311-P312-P330-P332+P313-P361-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


  • A10885

    Methanesulfonamide, 98+%
  • A13184

    Sodium acetate, anhydrous, 99%
  • A14930

    Terephthalaldehyde, 98%
  • 13404

    Lithium sulfate, anhydrous, 99.7% (metals basis)
  • 14130

    Potassium fluoride, anhydrous, 99%

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