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13716-12-6 - Tri-tert-butylphosphine, 96% - 10178 - Alfa Aesar

10178 Tri-tert-butylphosphine, 96%

CAS Number
13716-12-6
Synonyms

Size Price ($) Quantity Availability
1g 80.10
5g 252.90
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Tri-tert-butylphosphine, 96%

MDL
MFCD00015006
EINECS
237-266-4

Chemical Properties

Formula
C12H27P
Formula Weight
202.32
Form
Solid
Melting point
30°
Boiling Point
102-103°/13mm
Flash Point
-16°(-3°F)
Sensitivity
Air & Moisture Sensitive
Solubility
Insoluble in water. Soluble in alcohol and organic solvents

Applications

Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Notes

It is hygroscopic and incompatible with strong oxidizing agents. Stable under normal conditions.

GHS Hazard and Precautionary Statements

Hazard Statements: H250-H252-H314-H318

Catches fire spontaneously if exposed to air. Self-heating in large quantities; may catch fire. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P222-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P422a-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Store contents under inert gas. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.2
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
No

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