Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

1605-53-4 - Diethylphenylphosphine, 97% - 10180 - Alfa Aesar

10180 Diethylphenylphosphine, 97%

CAS Number
1605-53-4
Synonyms

Size Price ($) Quantity Availability
25g 424.00
Add to Cart Add to Quote Request View Item

Diethylphenylphosphine, 97%

MDL
MFCD00015172
EINECS
216-516-6

Chemical Properties

Formula
(C2H5)2P(C6H5)
Formula Weight
166.21
Form
Liquid
Boiling Point
220°
Flash Point
66°(150°F)
Density
0.954
Refractive Index
1.5475
Sensitivity
Air & Moisture Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

Diethylphenylphosphine is used as a catalyst for selective cross-dimerization, carboxyl migration reactions, selective hydrogenation, asymmetric induction by chiral diphosphines in ring contraction.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents, air, water/ moisture.

Literature References

F. Ramirez; D. Rhum; C.P. Smith. Reaction of diethylphenylphosphine with chloranil: Quinone-oxyphosphonium betaines and quinone-bis-oxyphosphonium dibetaines, a new type of stable phosphorus ylide. Tetrahedron. 1965, 21 (8), 1941-1959.

A.J. Deeming. Osmium-coordinated alkene and alkyne ligands derived from triethylphosphine and diethylphenylphosphine. AJournal of Organometallic Chemistry. 1977, 128, (1) 63-72.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H312-H331

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled.

Precautionary Statements: P210u-P261-P280-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware