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1605-53-4 - Diethylphenylphosphine, 97% - 10180 - Alfa Aesar

10180 Diethylphenylphosphine, 97%

CAS Number
1605-53-4
Synonyms

Size Price ($) Quantity Availability
1g 34.51
5g 136.99
25g 416.00
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Diethylphenylphosphine, 97%

MDL
MFCD00015172
EINECS
216-516-6

Chemical Properties

Formula
(C2H5)2P(C6H5)
Formula Weight
166.21
Form
Liquid
Boiling Point
220°
Flash Point
66°(150°F)
Density
0.954
Refractive Index
1.5475
Sensitivity
Air & Moisture Sensitive
Solubility
Not miscible or difficult to mix in water.

Applications

Diethylphenylphosphine is used as a catalyst for selective cross-dimerization, carboxyl migration reactions, selective hydrogenation, asymmetric induction by chiral diphosphines in ring contraction.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents, air, water/ moisture.

Literature References

F. Ramirez; D. Rhum; C.P. Smith. Reaction of diethylphenylphosphine with chloranil: Quinone-oxyphosphonium betaines and quinone-bis-oxyphosphonium dibetaines, a new type of stable phosphorus ylide. Tetrahedron. 1965, 21 (8), 1941-1959.

A.J. Deeming. Osmium-coordinated alkene and alkyne ligands derived from triethylphosphine and diethylphenylphosphine. AJournal of Organometallic Chemistry. 1977, 128, (1) 63-72.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H227

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Combustible liquid.

Precautionary Statements: P210-P261-P280-P304+P340-P311-P301+P312-P312-P363-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
No

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