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12092-47-6 - Chloro(1,5-cyclooctadiene)rhodium(I) dimer - Bis(1,5-cyclooctadiene)dirhodium(I) dichloride - 10466 - Alfa Aesar

10466 Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS Number
12092-47-6
Synonyms
Bis(1,5-cyclooctadiene)dirhodium(I) dichloride

Size Price ($) Quantity Availability
250mg 109.00
1g 357.00
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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

MDL
MFCD00012415
EINECS
235-157-6

Chemical Properties

Formula
C16H24Cl2Rh2
Formula Weight
493.08
Form
Crystalline
Melting point
243° dec.
Sensitivity
Air Sensitive & Hygroscopic
Solubility
Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.

Applications

It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.

Notes

This dimeric compound is air-stable. Slightly moisture sensitive in nature.

Literature References

Monney, A.; Nastri, F.; Albrecht, M. Peptide-Tethered Monodentate and Chelating Histidylidene Metal Complexes: Synthesis and Application in Catalytic Hydrosilylation. Dalt. Trans. 2013, 42, 5655.

Knowles, W. S. Asymmetric Hydrogenations (Nobel Lecture 2001). Adv. Synth. Catal. 2003, 345 (1-2), 3.

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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