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10468 Chlorotris(triphenylphosphine)rhodium(I), 97%

CAS Number
14694-95-2
Synonyms
Wilkinson's catalyst
Tris(triphenylphosphine)rhodium(I) chloride

Stock No. Size Price ($) Quantity Availability
10468-03 1g 124.00
10468-06 5g 529.00
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Chlorotris(triphenylphosphine)rhodium(I), 97%

MDL
MFCD00010016
EINECS
238-744-5

Chemical Properties

Formula
C54H45ClP3Rh
Formula Weight
925.23
Form
Micro Crystals
Melting point
ca 250° dec.
Storage & Sensitivity
Keep Cold.
Solubility
Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution

Applications

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.

Notes

Slowly decomposes in air

Literature References

D. A. Evans; G. C. Fu; A. H. Hoveyda. Rhodium(I)-catalyzed hydroboration of olefins: The documentation of regio- and stereochemical control in cyclic and acyclic systems. J. Am. Chem. Soc. 1988, 6917-6918. 

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,10047
Harmonized Tariff Code
2843.90
TSCA
Yes

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