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15337-84-5 - trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7% - 10484 - Alfa Aesar

10484 trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%

CAS Number
15337-84-5
Synonyms

Size Price ($) Quantity Availability
1g 67.95
5g 334.56
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trans-Dichlorobis(diethylsulfide)platinum(II), Pt 43.7%

MDL
MFCD00050943
EINECS
239-373-1

Chemical Properties

Formula
Pt[(C2H5)2S]2Cl2
Formula Weight
446.37
Form
Crystalline
Solubility
Soluble in acetone, alcohol, ethyl acetate and benzene

Applications

It is used in Hydrosilylation. Platinum(II) complexes of diethylsulfide are convenient and versatile precursor for the preparation of a variety of organoplatinum(II) derivatives.

Notes

Literature References

Tobita, H.; Habazaki, H.; Ogino, H. Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis- Dichlorobis(diethylsulfide)platinum(II) with Mesityllithium. Bull. Chem. Soc. 1987, 60, 797-799.

Momeni, B. Z.; Baleh, L. J.; Hamzeh, S.; Rominger, F. Insertion of SnCl2 into Pt-Cl bonds: synthesis and characterization of four- and five-coordinate trichlorostannylplatinum(II) complexes. J. Coord. Chem. 2007, 60 (3), 285-293.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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