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10493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

CAS Number
12107-56-1
Synonyms

Stock No. Size Price ($) Quantity Availability
10493-03 1g 113.00
10493-06 5g 515.00
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Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

MDL
MFCD00012412
EINECS
235-161-8

Chemical Properties

Formula
C8H12Cl2Pd
Formula Weight
285.49
Form
Crystalline
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in dichloromethane

Applications

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. It is sensitive to air. It is hygroscopic in nature. Incompatible with oxidizing agents.

Literature References

J.K. Stille.; D.E. James. The palladium(II)catalyzed olefin carbonylation reactions. The stereochemistry of the hydroxypalladation of cyclooctadiene . Journal of Organometallic Chemistry. 1976, 108 (3), 401-408.

Horst Kunkely, Arnd Vogler. Electronic spectrum and photoreactivity of dichloro(1,5-cyclooctadiene)-palladium(II). Journal of Organometallic Chemistry. 1998, 559 (1-2), 223-225.

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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