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Catalyst for C-C coupling reactions like Sonogashira coupling. Formation of host-guest complexes. Synthesis of mixed-metal, mixed-pyrimidine self-assembling metallacalix[n]arenes; ring-in-ring complex; binding of metal with glycose phosphates.
Bakherad, M.; Bahramian, B.; Nasr-Isfahani, H.; Ali Keivanloo, A.; Doostmohammadi, N. Polystyrene-supported Palladium(II) Ethylenediamine Complex: A highly Active and Recyclable Catalyst for the Synthesis of 2-Benzylimidazo[2,1-b]pyridines through Heteroannulation of acetylenic Compounds. J. Heterocycl. Chem. 2009, 46 (1), 100-104.
Bardají, E. G.; Freisinger, E.; Costisella, B.; Schalley, C. A.; Brüning, W.; Sabat, M.; Lippert, B. Mixed-Metal (Platinum, Palladium), Mixed-Pyrimidine (Uracil, Cytosine) Self-Assembling Metallacalix[n]arenes: Dynamic Combinatorial Chemistry with Nucleobases and Metal Species. Chem. Eur. J. 2007, 13 (21), 6019-6039.
Bach, S. B. H.; Green, C. E.; Nagore, L. I.; Sepeda, T. G.; Merrill, G. N. Complexes of dichloro(ethylenediamine)palladium(II) observed from aqueous solutions by electrospray mass spectrometry. J. Am. Soc. Mass Spectrom. 2007, 18 (4), 769-777.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.