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15635-87-7 - Iridium(III) 2,4-pentanedionate, Ir 37.5% min - Iridium(III) acetylacetonate - 10514 - Alfa Aesar

10514 Iridium(III) 2,4-pentanedionate, Ir 37.5% min

CAS Number
15635-87-7
Synonyms
Iridium(III) acetylacetonate

Size Price ($) Quantity Availability
0.25g 56.65
1g 214.24
5g 683.10
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Iridium(III) 2,4-pentanedionate, Ir 37.5% min

MDL
MFCD00015353
EINECS
239-711-8

Chemical Properties

Formula
C15H21IrO6
Formula Weight
489.53
Form
Crystalline
Melting point
269-271°
Solubility
Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol.

Applications

It is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.

Notes

Stable in air.

Literature References

Vuoria, H.; Pasanenc, A.; Lindbladb, M.; Valdenc, M.; Niemeläa, M. V.; Krausea A. O. I. The Effect of Iridium Precursor on Oxide-supported Iridium Catalysts Prepared by Atomic Layer Deposition. Appl. Surf. Sci. 2011, 257 (9), 4204-4210.

Nassreddine, S.; Bergeret, G.; Jouguet, B.; Geantet, C.; Piccolo, L.. Operando study of Iridium Acetylacetonate Decomposition on Amorphous Silica-alumina for Bifunctional Catalyst Preparation. Phys. Chem. Chem. Phys. 2010, 12 (28), 7812-20.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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