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3375-31-3 - Palladium(II) acetate, Pd 45.9-48.4% - Acetic acid palladium(II) salt - Palladium diacetate - 10516 - Alfa Aesar

10516 Palladium(II) acetate, Pd 45.9-48.4%

CAS Number
3375-31-3
Synonyms
Acetic acid palladium(II) salt
Palladium diacetate

Size Price ($) Quantity Availability
1g 73.50
5g 269.00
25g 862.00
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Palladium(II) acetate, Pd 45.9-48.4%

MDL
MFCD00012453
EINECS
222-164-4

Chemical Properties

Formula
C12H18O12Pd3
Formula Weight
673.46
Form
Needles
Melting point
ca 205° dec.
Solubility
Soluble as monomer in glacial acetic acid or as trimer in benzene.

Applications

Palladium(II)acetate is a catalyst of choice for a wide variety of reactions such as vinylation, Wacker process, Buchwald-Hartwig amination, carbonylation, oxidation, rearrangement of dienes (e.g., Cope rearrangement), C-C bond formation, reductive amination, etc. Precursor to Pd(0), other Pd(II) compounds of catalytic significance, and Pd nanowires.

Notes

Palladium(II) acetate decomposes to palladium on warming in alcoholic solutions, or on heating in other organic solvents. It is not compatible with strong oxidizing agents.

Literature References

Zhang, S.; Shi, L.; Ding, Y. Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity. J. Am. Chem. Soc. 2011, 133 (50), 20218-20229.

Albert, J.; Granell, J.; Tavera, R. On the Mechanism of the Cyclopalladation Reaction of Benzyl-benzylidene-Amine with Palladium(II)acetate in Acetic acid. J. Organomet. Chem. 2003, 667, 192-196.

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H317

Causes serious eye damage. May cause an allergic skin reaction.

Precautionary Statements: P261-P280a-P305+P351+P338-P310a-P363-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor Wash contaminated clothing before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6991
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
AJ9000000

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