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10516 Palladium(II) acetate, Pd 45.9-48.4%

CAS Number
3375-31-3
Synonyms
Acetic acid palladium(II) salt
Palladium diacetate

Stock No. Size Price ($) Quantity Availability
10516-03 1g 76.50
10516-06 5g 279.00
10516-14 25g 897.00
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Palladium(II) acetate, Pd 45.9-48.4%

MDL
MFCD00012453
EINECS
222-164-4

Chemical Properties

Formula
C12H18O12Pd3
Formula Weight
673.46
Form
Needles
Melting point
ca 205° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble as monomer in glacial acetic acid or as trimer in benzene.

Applications

Palladium(II)acetate is a catalyst of choice for a wide variety of reactions such as vinylation, Wacker process, Buchwald-Hartwig amination, carbonylation, oxidation, rearrangement of dienes (e.g., Cope rearrangement), C-C bond formation, reductive amination, etc. Precursor to Pd(0), other Pd(II) compounds of catalytic significance, and Pd nanowires.

Notes

Palladium(II) acetate decomposes to palladium on warming in alcoholic solutions, or on heating in other organic solvents. It is not compatible with strong oxidizing agents.

Literature References

Zhang, S.; Shi, L.; Ding, Y. Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity. J. Am. Chem. Soc. 2011, 133 (50), 20218-20229.

Albert, J.; Granell, J.; Tavera, R. On the Mechanism of the Cyclopalladation Reaction of Benzyl-benzylidene-Amine with Palladium(II)acetate in Acetic acid. J. Organomet. Chem. 2003, 667, 192-196.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H318

May be corrosive to metals. Causes serious eye damage.

Precautionary Statements: P234-P280-P305+P351+P338-P310-P390

Keep only in original container. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage.

Other References

Merck
14,6991
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
AJ9000000

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