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14024-61-4 - Palladium(II) 2,4-pentanedionate, Pd 34.7% - Palladium(II) acetylacetonate - Bis(acetylacetonato)palladium(II) - 10517 - Alfa Aesar

10517 Palladium(II) 2,4-pentanedionate, Pd 34.7%

CAS Number
14024-61-4
Synonyms
Palladium(II) acetylacetonate
Bis(acetylacetonato)palladium(II)

Size Price ($) Quantity Availability
1g 64.60
5g 285.00
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Palladium(II) 2,4-pentanedionate, Pd 34.7%

MDL
MFCD00000025
EINECS
237-859-8

Chemical Properties

Formula
C10H14O4Pd
Formula Weight
304.92
Form
Powder
Melting point
210° dec.
Solubility
Soluble in benzene and chloroform.

Applications

It is used in carbonylation, oligomerization, and as a catalyst precursor for various synthetic organic transformations, for example in the preparation of complexes to efficiently catalyze Heck reaction. Useful in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides, in the preparation of monodisperse nanoparticles of CuPd alloy and in several cross-coupling reactions.

Notes

Stored in a cool, dry place in a tightly closed container.

Literature References

Wang, Y.; Hu, J.; Cai, Y.; Xu, S.; Weng, B.; Peng, K.; Wei, X.; Wei, T.; Zhou, H.; Li, X.; Liang, G. An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. J. Med. Chem. 2013, 56 (23), 9601-9611.

Huang, L.; Wang, Y.; Wang, Z.; Chen, F.; Tan, J.; Wong, P. K. Heck Chemistry - a Highly Active Ligand-Free Metal Catalyst System in Situ Generated from PdII Supported on SiO2. Phys. Chem. 2012, 2 (1), 27-34.

Hamid, M.; Zeller, M.; Hunter, A. D.; Mazhar, M.; Tahir, A. A.; Redetermination of bis¬(2,4-pentane¬dionato)¬palladium(II). Acta Crystallogr. E 2005, 61 (11), 2181-2183.

GHS Hazard and Precautionary Statements

Hazard Statements: H318

Causes serious eye damage.

Precautionary Statements: P280-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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