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10026-13-8 - Phosphorus(V) chloride, 98% - 10523 - Alfa Aesar

10523 Phosphorus(V) chloride, 98%

CAS Number
10026-13-8
Synonyms

Size Price ($) Quantity Availability
100g 30.96
500g 41.73
*4x500g 125.53
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Phosphorus(V) chloride, 98%

MDL
MFCD00011439
EINECS
233-060-3

Chemical Properties

Formula
PCl5
Formula Weight
208.24
Form
Solid
Melting point
162° subl.
Density
2.114
Sensitivity
Moisture Sensitive
Solubility
Soluble in carbon disulfide and carbon tetrachloride.

Applications

Phosphorus(V) chloride can be used for both oxidative and substitutive chlorinations, & for both organic and inorganic compounds. Dehydrating agent. Precursor to Vilsmeier reagent, lithium hexafluorophosphate electrolyite for lithium batteries.

Notes

Phosphorus(V) chloride is moisture-sensitive, & reacts violently with water. Non-flammable.

Literature References

Suter, R. W.; Knachel, H. C.; Petro, V. P.; Howatson, J. H.; S. G. Shore, S. G. Nature of Phosphorus(V) Chloride in Ionizing and Nonionizing Solvents. J. Am. Chem. Soc. 1978, 95 (5), 1474-1479.

Mitrasov, Y. N.; Sosnov, D. A.; Kondrat’eva, O. V. Reaction of Spiro[2.2]pentane with Phosphorus pentachloride. Russ. J. Gen. Chem. 2013, 83 (6), 1167.

GHS Hazard and Precautionary Statements

Hazard Statements: H330-H302-H314-H373

Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P301+P330+P331-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. IF SWALLOWED: Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7351
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2812.10
TSCA
Yes
RTECS
TB6125000

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