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14323-36-5 - Potassium tetracyanoplatinate(II) trihydrate, 99.9% (metals basis), Pt 44.9% min - 10536 - Alfa Aesar

10536 Potassium tetracyanoplatinate(II) trihydrate, 99.9% (metals basis), Pt 44.9% min

CAS Number
14323-36-5
Synonyms

Size Price ($) Quantity Availability
1g 143.17
5g 516.80
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Potassium tetracyanoplatinate(II) trihydrate, 99.9% (metals basis), Pt 44.9% min

MDL
MFCD00149921
EINECS
209-236-0

Chemical Properties

Formula
C4N4K2Pt•3H2O
Formula Weight
431.42 (377.37anhy)
Form
Crystalline
Solubility
Soluble in hot water

Applications

Potassium tetracyanoplatinate(II) trihydrate is used in the preparation other salts like Krogmann's salt, that are highly conducting, one dimensional materials.

Notes

Hygroscropic. Incompatible with strong acids, strong bases and strong oxidising agents. Store in a dry, cool place in a tightly closed container.

Literature References

Maynard, B. A.; Smith, P. A.; Jaleel, A.; Ladner, L.; Sykora, R. E. Structural Modulation in Lanthanide Tetracyanoplatinates Incorporating Terpyridine: Synthesis and Structures of Four Distinct One-Dimensional Variants. J. Chem. Crystallogr. 2010, 40 (7), 616-623.

Ding, S.; Jones, N. D.; McDowell, C. A. Potassium Tetracyanoplatinate (II) Trihydrate (K2Pt(CN)4 x 3H2O) Studied by High resolution Solid State 13C MAS NMR, Solid State, Nucl. Magn. Reson. 1998, 10 (4), 205-10.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P311-P362-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7685
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes

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