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10548 Tetrakis(triphenylphosphine)palladium(0), 99.8% (metals basis), Pd 9% min

CAS Number
14221-01-3
Synonyms
Palladium(0) tetrakis(triphenylphosphine)

Stock No. Size Price ($) Quantity Availability
10548-02 0.5g 24.00
10548-04 2g 66.40
10548-09 10g 251.00
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Tetrakis(triphenylphosphine)palladium(0), 99.8% (metals basis), Pd 9% min

MDL
MFCD00010012
EINECS
238-086-9

Chemical Properties

Formula
Pd[P(C6H5)3]4
Formula Weight
1155.57
Form
Crystalline
Melting point
100-105°
Storage & Sensitivity
Store at -20°C. Air Sensitive. Store under Argon.
Solubility
Insoluble in water. Soluble in benzene, ethanol and chloroform

Applications

Widely used as a catalyst for palladium-catalyzed coupling reactions including Suzuki coupling, Sonogashira coupling, Heck reaction, Negishi coupling and Stille coupling. Used in isomerization, carbonylation, oxidation, and C-C bond formation reactions.

Notes

Heat sensitive. Store below 4ƒ °C in tighlty closed containers, protected from light and air. Incompatible with strong oxidizing agents.

Literature References

Agrios, K. A.; Srebnik, M. Reduction of Benzylic Halides with Diethylzinc Using Tetrakis(triphenylphosphine)palladium as Catalyst. J. Org. Chem. 1993, 58 (24), 6908-6910.

Lin, D. W.; Masuda, T.; Biskup, M. B.; Nelson, J. D.; Baran, P. S. Synthesis-Guided Structure Revision of the Sarcodonin, Sarcoviolin and Hydnellin Natural Product Family. J Org Chem. 2011, 76 (4), 1013-1030.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H500

Harmful if swallowed. May form combustible dust concentrations in air

Precautionary Statements: P264b-P270-P301+P312-P330-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
6704828
Harmonized Tariff Code
2843.90
TSCA
Yes

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