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14284-92-5 - Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), Rh 25.2% min - Rhodium(III) acetylacetonate - 10561 - Alfa Aesar

10561 Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), Rh 25.2% min

CAS Number
14284-92-5
Synonyms
Rhodium(III) acetylacetonate

Size Price ($) Quantity Availability
0.5g 194.40
1g 393.30
5g 1775.70
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Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), Rh 25.2% min

MDL
MFCD00083144
EINECS
238-192-5

Chemical Properties

Formula
C15H21O6Rh
Formula Weight
400.23
Form
Crystalline
Melting point
263-264°
Solubility
Very soluble in chloroform. Soluble in alcohol. In soluble in water.

Applications

Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.

Notes

Rhodium(III) 2,4-pentanedionate is stable under normal conditions of storage and use.

Literature References

Xie, S.; Liu, X. Y.; Xia, Y. Shape-Controlled Syntheses of Rhodium Nanocrystals for the Enhancement of their Catalytic Properties. Nano. Res. 2015, 8 (1), 82-96.

Jia, Z.; Harrell, J. W.; Misra, R. D. K. Synthesis and magnetic properties of self-assembled FeRh nanoparticles. Appl. Phys. Lett. 2008, 93 (2), 022504.

Liguras, D. K..; Kondarides, D. I.; Verykios, X. E. Production of Hydrogen for Fuel Cells by Steam Reforming of Ethanol Over Supported Noble Metal Catalysts. Appl. Catal. B. Environ. 2003, 43, 345-354.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P363-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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