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10361-44-1 - Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10657 - Alfa Aesar

10657 Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

CAS Number
10361-44-1
Synonyms

Size Price ($) Quantity Availability
25g 78.69
100g 233.81
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Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00003460
EINECS
233-791-8

Chemical Properties

Formula
Bi(NO3)3•xH2O
Formula Weight
394.99(anhy)
Form
Crystalline
Melting point
30° dec.
Sensitivity
Hygroscopic
Solubility
Slightly soluble in water; soluble in acetone, acetic acid, and glycerol. Insoluble in ethyl acetate and ethanol.

Applications

It is used in electronic ceramics and fluorescent paints. It is employed as an oxidant for selective oxidation of sulfides to sulfoxides, as a nitrating reagent for synthesizing nitro aromatic compounds, and as a precursor for Dragendorff reagent for use in TLC stain and for testing the presence of alkaloids. On silica gel support, it has been reported to be an efficient catalyst for the Biginelli reaction.

Notes

Hygroscopic. Stable. On heating it decomposes to form nitrogen dioxide. Incompatible with strong acids, strong reducing agents, organic materials, and finely powdered metals.

Literature References

Polanki, I. K.; Kurma, S. H.; Bhattacharya, A. K. Direct Glycosylation of Unprotected and Unactivated Sugars Using Bismuth Nitrate Pentahydrate. J. Carbohydr. Chem. 2015, 34 (4), 196-205.

Miersch, L.; Schlesinger, M.; Troff, R. W.; Schalley, C. A.; Rüffer, T.; Heinrich Lang, H.; Zahn, D.; Mehring, M. Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters. Chem-Eur. J. 2011, 17 (25), 6985-6990.

Park, Y.; McDonald, K. J.; Choi, K. Progress in Bismuth Vanadate Photoanodes for Use in Solar Water Oxidation. Chem. Soc. Rev. 2013, 42, 2321-2337.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,1271
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2834.29
TSCA
Yes

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