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13778-31-9 - Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10699 - Alfa Aesar

10699 Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

CAS Number
13778-31-9
Synonyms

Size Price ($) Quantity Availability
5g 23.70
25g 60.40
100g 187.00
500g 567.00
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Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149669
EINECS
221-838-5

Chemical Properties

Formula
CuN2O6•xH2O
Formula Weight
187.55(anhy)
Form
Crystalline Aggregates
Sensitivity
Hygroscopic
Solubility
Soluble in ethanol and water. Insoluble in ethyl acetate.

Applications

It serves as a catalyst for oxidative coupling of 2,6-dimethylphenol, resulting in an important engineering polymer material. Also used in textiles and polishing agents for other metals. It is a precursor for copper oxide, which finds use as a catalyst for many organic transformations. Menke conditions employ copper nitrate for aromatic nitrations. Claycop reagent, the hydrated copper nitrate deposited on clay, finds use in many organic reactions, for example, oxidation of dithioacetals to carbonyls and thiols to disulfides.

Notes

Hygroscopic. On heating, it forms basic copper nitrate containing hydroxy anions, and on further heating, it forms cupric oxide liberating nitrogen dioxide and oxygen.

Literature References

Gascon, J.; Aguado, S.; Kapteijn, F. Manufacture of Dense Coatings of Cu3(BTC)2 (HKUST-1) on alpha-Alumina. Micropor. Mesopor. Mat. 2008, 113 (1-3), 132-138.

El-Shall, M. S.; Abdelsayed, V.; Khder, A. E. R. S.; Hassan, H. M. A.; El-Kaderi, H. M.; Reich, T. E. Metallic and Bimetallic Nanocatalysts Incorporated into Highly Porous Coordination Polymer MIL-101. J. Mater. Chem. 2009, 19, 7625-7631.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H302-H314-H318

May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P221-P210v-P303+P361+P353-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,2643
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
GL7875000

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