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10699 Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

CAS Number
13778-31-9
Synonyms

Stock No. Size Price ($) Quantity Availability
10699-06 5g 25.70
10699-14 25g 63.70
10699-22 100g 201.00
10699-36 500g 619.00
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Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149669
EINECS
221-838-5

Chemical Properties

Formula
CuN2O6•xH2O
Formula Weight
187.55(anhy)
Form
Crystalline Aggregates
Storage & Sensitivity
Hygroscopic. Keep Cold.
Solubility
Soluble in ethanol and water. Insoluble in ethyl acetate.

Applications

It serves as a catalyst for oxidative coupling of 2,6-dimethylphenol, resulting in an important engineering polymer material. Also used in textiles and polishing agents for other metals. It is a precursor for copper oxide, which finds use as a catalyst for many organic transformations. Menke conditions employ copper nitrate for aromatic nitrations. Claycop reagent, the hydrated copper nitrate deposited on clay, finds use in many organic reactions, for example, oxidation of dithioacetals to carbonyls and thiols to disulfides.

Notes

Hygroscopic. On heating, it forms basic copper nitrate containing hydroxy anions, and on further heating, it forms cupric oxide liberating nitrogen dioxide and oxygen.

Literature References

Gascon, J.; Aguado, S.; Kapteijn, F. Manufacture of Dense Coatings of Cu3(BTC)2 (HKUST-1) on alpha-Alumina. Micropor. Mesopor. Mat. 2008, 113 (1-3), 132-138.

El-Shall, M. S.; Abdelsayed, V.; Khder, A. E. R. S.; Hassan, H. M. A.; El-Kaderi, H. M.; Reich, T. E. Metallic and Bimetallic Nanocatalysts Incorporated into Highly Porous Coordination Polymer MIL-101. J. Mater. Chem. 2009, 19, 7625-7631.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H314-H335

May intensify fire; oxidizer. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2643
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
GL7875000

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