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1313-13-9 - Manganese(IV) oxide, Puratronic®, 99.996% (metals basis) - 10805 - Alfa Aesar

10805 Manganese(IV) oxide, Puratronic®, 99.996% (metals basis)

CAS Number
1313-13-9
Synonyms

Size Price ($) Quantity Availability
5g 43.10
25g 140.08
100g 449.08
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Manganese(IV) oxide, Puratronic®, 99.996% (metals basis)

MDL
MFCD00003463
EINECS
215-202-6

Chemical Properties

Formula
MnO2
Formula Weight
86.94
Form
Powder
Melting point
535° dec.
Density
5.026
Solubility
Insoluble in water

Applications

It is used as an oxidizing agent in organic synthesis such as oxidation of allylic/benzylic alcohols, as a textile dye, as a reducing agent, and as a component of dry cell batteries such as zinc-carbon battery and alkaline battery. It is also used in making pigments for glasses and ceramics, and drier for paints. Further it is used in the manufacture of manganese steel and several manganese derivatives including potassium permanganate, a powerful versatile oxidant. Catalytic hydration of nitriles to amides by flowing through manganese dioxide has been reported. Manganese dioxide supported on inorganic oxide can be used for oxidation of methylamine through CWAO (Catalytic Wet Air Oxidation). It has high potential as highly efficient and robust material for water oxidation reaction (WORs).

Notes

At temperatures above 550°C, manganese (IV) oxide forms manganese (III) oxide and oxygen. It can slightly stain the skin, which can be washed off with some rubbing.

Literature References

Li, B.; Yan, H.; Ma, J.; Yu, P.; Xia, D.; Huang, W.; Chu, W.; Wu, Z. Manipulating the Electronic Structure of Li-Rich Manganese-Based Oxide Using Polyanions: Towards Better Electrochemical Performance. Adv. Funct. Mater. 2014, 24 (32), 5112-5118.

Acznik, I.; Lota, K.; Sierczynska, A.; Lota, G. Carbon-Supported Manganese Dioxide as Electrode Material for Asymmetric Electrochemical Capacitors. Int. J. Electrochem. Sci. 2014, 9, 2518 - 2534.

Kuo, C. -H.; Mosa, I. M.; Poyraz, A. S.; Biswas, S.; El-Sawy, A. M.; Song, W.; Luo, Z.; Chen, S. -Y.; Rusling, J. F.; He, J.; Suib, S. L. Robust Mesoporous Manganese Oxide Catalysts for Water Oxidation. ACS Catal. 2015, 5 (3), 1693-1699.

Battilocchio, C.; Hawkins, J. M.; Ley, S. V. Mild and Selective Heterogeneous Catalytic Hydration of Nitriles to Amides by Flowing through Manganese Dioxide. Org. Lett. 2014, 16 (4), 1060-1063.

Chi, H. Z.; Li, Y.; Xin, Y.; Qin, H. Boron-doped manganese dioxide for supercapacitors. Chem. Commun. 2014, 50, 13349-13352.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H332

Harmful if swallowed. Harmful if inhaled.

Precautionary Statements: P261-P264-P270-P271-P304+P340-P301+P312-P312-P330-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5730
Harmonized Tariff Code
2820.10
TSCA
Yes
RTECS
OP0350000

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