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11030 Iridium(III) chloride hydrate, 99.8% (metals basis)

CAS Number
14996-61-3
Synonyms

Stock No. Size Price ($) Quantity Availability
11030-03 1g 104.00
11030-06 5g 375.00
11030-14 25g 1737.00
50g Pricing available on request. Click Bulk Quote button and specify size.
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Iridium(III) chloride hydrate, 99.8% (metals basis)

MDL
MFCD00149750
EINECS
233-044-6

Chemical Properties

Formula
IrCl3•xH2O
Formula Weight
298.56(anhy)
Form
Crystalline
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water and alcohol.

Applications

Iridium(III) chloride hydrate is used to prepare other iridium compounds. It finds use as a catalyst for oxidation in presence of cerium(IV) and in the the manufacture of electrodes. Iridium(III) chloride is used in iridium electroplating, in making the standard meter bar of Paris and crucibles. It is used for high temperature electrical contacts, as hardening agent, in tipping pens and compass bearings and Pt/Ir spark plugs. It is used for medical, surgical or other patient oriented applications, MMO (mixed metal oxide) titanium electrode coatings and as a starting material for heterogeneous catalysts.

Notes

Hygroscopic and Incompatible with strong oxidants.

Literature References

Botelho, M. B. S.; Hernandez, J. M. F.; Queiroz, T. B.; Eckert, H.; Cola, L.; Camargo, A. S. S. Iridium(iii)-surfactant complex immobilized in mesoporous silica via templated synthesis: a new route to optical materials. J. Mater. Chem. 2011, 21, 8829-8834.

Tandon, P. K. ; Sahgal, S.; Srivastava, M.; Singh, S. B. Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2. Appl. Organomet. Chem. 2007, 21 (3), 135-138.

Tandon, P. K.; Sahgal, S.; Gayatri; Purwar, M.; Dhusia, M. Oxidation of Ketones by Cerium(IV) in Presence of Iridium(III) Chloride. J. Mol. Catal. A: Chem. 2006, 250 (1-2), 203-209.

Tandon, P. K.; Singh, A. K.; Sahgal, S.; Kumar, S. Oxidation of Cyclic Alcohols by Cerium(IV) in Acidic Medium in the Presence of Iridium(III) chloride. J. Mol. Catal. A: Chem. 2008, 282 (1-2), 136-143.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5088
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes

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