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14898-67-0 - Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min - 11043 - Alfa Aesar

11043 Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

CAS Number
14898-67-0
Synonyms

Size Price ($) Quantity Availability
2g 70.84
10g 244.45
50g 927.00
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Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

MDL
MFCD00149844
EINECS
233-167-5

Chemical Properties

Formula
Cl3Ru•xH2O
Formula Weight
207.43(anhy)
Form
Crystalline Soluble
Melting point
100°dec
Sensitivity
Hygroscopic
Solubility
Very soluble in water. Soluble in alcohol, acetone.

Applications

Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs’ catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

Notes

Hygroscopic. Incompatible with zinc.

Literature References

Wang, J.; Zhao, J.; Osterloh, F. E. Photochemical charge transfer observed in nanoscale hydrogen evolving photocatalysts using surface photovoltage spectroscopy. Energy Environ. Sci. 2015, 8 (10), 2970-2976.

Nazarov, A. A.; Meier, S. M.; Zava, O.; Nosova, Y. N.; Milaeva, E. R.; Hartinger, C. G.; Dyson, P. J. Protein ruthenation and DNA alkylation: chlorambucil-functionalized RAPTA complexes and their anticancer activity. Dalton Trans. 2015, 44 (8), 3614-3623.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H290-H302-H412

Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals. Harmful if swallowed. Harmful to aquatic life with long lasting effects.

Precautionary Statements: P260-P273-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8302
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
VM2650000

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