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11044 Platinum(II) chloride, 99.9% (metals basis), Pt 73% min

CAS Number
10025-65-7
Synonyms

Stock No. Size Price ($) Quantity Availability
11044-03 1g 219.00
11044-06 5g 860.00
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Platinum(II) chloride, 99.9% (metals basis), Pt 73% min

MDL
MFCD00011181
EINECS
233-034-1

Chemical Properties

Formula
Cl2Pt
Formula Weight
266.00
Form
Crystalline
Melting point
581° dec.
Density
5.87
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ammonia and hydrochloric acid. Insoluble in water, alcohol and ether.

Applications

Platinum(II) chloride is used as a catalyst for a variety of C-C bond, C-O bond and C-N bond formation reactions. It acts as a precursor to prepare other platinum compounds such as cisplatin and dichloro(cycloocta-1,5-diene)platinum(II). It is a well known chemotherapy drug.

Notes

Incompatible with strong oxidizing agents.

Literature References

Sivaraman, M.; Perumal, P. T. Synthesis of tetracyclic chromenones via platinum(II) chloride catalysed cascade cyclization of enediyne-enones. Org. Biomol. Chem. 2014, 12 (8), 1318-1327.

Schelwies, M.; Farwick, A.; Rominger, F.; Helmchen, G. Platinum(II) Chloride-Catalyzed Stereoselective Domino Enyne Isomerization/Diels- Alder Reaction. J. Org. Chem. 2010, 75 (22), 7917-7919.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H317-H334

Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements: P260-P264b-P272-P280-P285-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P333+P313-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7528
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
TP2275000

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