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11323 Cerium(IV) sulfate hydrate, REacton®, 99% (REO)

CAS Number
95838-16-7
Synonyms

Stock No. Size Price ($) Quantity Availability
11323-22 100g 84.40
11323-36 500g 350.00
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Cerium(IV) sulfate hydrate, REacton®, 99% (REO)

MDL
MFCD00149427
EINECS
237-029-5

Chemical Properties

Formula
Ce(SO4)2•xH2O
Formula Weight
332.24(anhy)
Form
Crystalline
Melting point
195° dec.
Density
3.01
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Slightly soluble in water. Soluble in dil.sulfuric acid.

Applications

Cerium(IV) sulfate hydrate acts as oxidizing agent which is used for the generation of o-benzoquinone from catechol. It promotes the formation of radicals from dialkyl malonates, which undergo substitution reactions with furans and thiophenes.

Notes

Incompatible with reducing agents and oxidizing agents.

Literature References

Asutay, O.; Hamarat, N.; Uludag, N.; Coşkun, N. Selective oxidative deoximation with anhydrous Ce(IV) sulfate. Tetrahedron Lett. 2015,56 (25), 3902-3904.

Zhang, Q.; Wu, D.; Wu, J.; Ou, Y.; Mu, C.; Han, B.; Zhang, Q. Improved blood-brain barrier distribution: Effect of borneol on the brain pharmacokinetics of kaempferol in rats by in vivo microdialysis sampling. J. Ethnopharmacol. 2015, 162, 270-277.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H314-H335

May intensify fire; oxidizer. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2846.10
TSCA
Yes
RTECS
WS6960000

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