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95838-16-7 - Cerium(IV) sulfate hydrate, REacton®, 99% (REO) - 11323 - Alfa Aesar

11323 Cerium(IV) sulfate hydrate, REacton®, 99% (REO)

CAS Number
95838-16-7
Synonyms

Size Price ($) Quantity Availability
100g 82.71
500g 342.99
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Cerium(IV) sulfate hydrate, REacton®, 99% (REO)

MDL
MFCD00149427
EINECS
237-029-5

Chemical Properties

Formula
Ce(SO4)2•xH2O
Formula Weight
332.24(anhy)
Form
Crystalline
Melting point
195° dec.
Density
3.01
Sensitivity
Moisture Sensitive
Solubility
Slightly soluble in water. Soluble in dil.sulfuric acid.

Applications

Cerium(IV) sulfate hydrate acts as oxidizing agent which is used for the generation of o-benzoquinone from catechol. It promotes the formation of radicals from dialkyl malonates, which undergo substitution reactions with furans and thiophenes.

Notes

Incompatible with reducing agents and oxidizing agents.

Literature References

Asutay, O.; Hamarat, N.; Uludag, N.; Coşkun, N. Selective oxidative deoximation with anhydrous Ce(IV) sulfate. Tetrahedron Lett. 2015,56 (25), 3902-3904.

Zhang, Q.; Wu, D.; Wu, J.; Ou, Y.; Mu, C.; Han, B.; Zhang, Q. Improved blood-brain barrier distribution: Effect of borneol on the brain pharmacokinetics of kaempferol in rats by in vivo microdialysis sampling. J. Ethnopharmacol. 2015, 162, 270-277.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H272

Causes severe skin burns and eye damage. May intensify fire; oxidizer.

Precautionary Statements: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2846.10
TSCA
Yes
RTECS
WS6960000

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