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Rhenium(VII) oxide acts as a precursor to methylrhenium trioxide, organorhenium oxides which catalyze olefin oxidation, metathesis and other transformations. It is used as a reagent for dehydrations and rearrangements of allylic alcohols, oximes and amides, oxidative cyclizations, alkene metathesis and formation of bisperoxyacetals.
Bernier, M. C.; Wysocki, V. H.; Dagan, S. Laser desorption ionization of small molecules assisted by tungsten oxide and rhenium oxide particles. J. Mass Spectrom. 2015, 50 (7), 891-898.
Murphy, N. R.; Gallagher, R. C.; Sun, L.; Jones, J. G.; Grant, J. T. Optical and chemical properties of mixed-valent rhenium oxide films synthesized by reactive DC magnetron sputtering. Opt. Mater. 2015, 45, 191-196.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant