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Iron(III) fluroide is used in ceramics manufacturing. It is used as a catalyst for certain cross coupling reactions. Further, it is involved in the chemoselective addition of cyanide to aldehyde to prepare cyanohydrins.
Song, H.; Yang, G.; Cui, H.; Wang, C. Honeycomb-like porous iron fluoride hybrid nanostructures: excellent Li-storage properties and investigation of the multi-electron reversible conversion reaction mechanism. J. Mater. Chem. A 2015, 3 (39), 19832-19841.
Shiga, K.; Yamada, Y.; Kobayashi, Y. Mössbauer study of iron fluoride films produced by pulsed laser deposition. J. Radioanal. Nucl. Chem. 2015, 303 (2), 1477-1480.