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21324-40-3 - Lithium hexafluorophosphate, 98% - 11529 - Alfa Aesar

11529 Lithium hexafluorophosphate, 98%

CAS Number
21324-40-3
Synonyms

Size Price ($) Quantity Availability
1g 34.60
10g 52.90
50g 178.00
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Lithium hexafluorophosphate, 98%

MDL
MFCD00011096
EINECS
244-334-7

Chemical Properties

Formula
LiPF6
Formula Weight
151.90
Form
Powder
Melting point
200° dec.
Density
1.5
Sensitivity
Moisture Sensitive
Solubility
Soluble in water.

Applications

Used as an electrolyte in Li-ion batteries.Lithium hexafluorophosphate is used as an electrolyte in lithium batteries, ceramic industries and for welding electrode manufacturing. It is also used in commercial secondary batteries, prism spectrometer and x-ray monochromator. Further, it catalyzes the tetrahydropyranylation of tertiary alcohol.

Notes

Hygroscopic. Air and moisture sensitive. Incompatible with strong oxidizing agents, strong acids.

Literature References

Wang, D. Y.; Xiao, A.; Wells, L.; Dahn, J. R. Effect of Mixtures of Lithium Hexafluorophosphate (LiPF6) and Lithium Bis (fluorosulfonyl) imide (LiFSI) as Salts in Li [Ni1/3Mn1/3Co1/3]O2/Graphite Pouch Cells. J. Electrochem. Soc. 2015, 162 (1), A169-A175.

Kraft, V.; Grützke, M.; Weber, W.; Menzel, J.; Wiemers-Meyer, S.; Winter, M.; Nowak, S. Two-dimensional ion chromatography for the separation of ionic organophosphates generated in thermally decomposed lithium hexafluorophosphate-based lithium ion battery electrolytes. J. Chromatogr. A 2015, 1409, 201-209.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H311-H314-H318

Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2826.90
TSCA
Yes

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