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26042-64-8 - Silver hexafluoroantimonate, 99% - 11538 - Alfa Aesar

11538 Silver hexafluoroantimonate, 99%

CAS Number
26042-64-8
Synonyms

Size Price ($) Quantity Availability
1g 17.15
5g 49.13
25g 174.40
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Silver hexafluoroantimonate, 99%

MDL
MFCD00003401
EINECS
247-429-1

Chemical Properties

Formula
AgSbF6
Formula Weight
343.41
Form
Powder/Lump
Sensitivity
Light Sensitive & Hygroscopic
Solubility
Soluble in water.

Applications

Silver hexafluoroantimonate is used as a catalyst for the preparation of a number of compounds. It acts as an acidic catalyst in epoxide opening reactions and sulfenylation reactions , controlled initiator in polymerization reactions, and as an activator of catalyst in certain organic reactions.

Notes

Stable at room temperature. Hygroscopic, light sensitive, very corrosive, and incompatible with strong oxidizing agents.

Literature References

Li, J.; Liu, Y.; Li, C.; Jia, X. Silver Hexafluoroantimonate-Catalyzed Three-Component [2+2+1]?Cycloadditions of Allenoates, Dual Activated Olefins, and Isocyanides. Advanced Synthesis & Catalysis 2011, 353 (6), 913-917.

Briones, J. F.; Davies, H. M. L. Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers. J. Am. Chem. Soc. 2013, 135 (36), 13314-13317.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H302-H332-H411

Causes severe skin burns and eye damage. Harmful if swallowed. Harmful if inhaled. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P260-P261-P273-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.29
TSCA
Yes

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