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11538 Silver hexafluoroantimonate, 99%

CAS Number
26042-64-8
Synonyms

Stock No. Size Price ($) Quantity Availability
11538-03 1g 20.00
11538-06 5g 51.20
11538-14 25g 222.00
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Silver hexafluoroantimonate, 99%

MDL
MFCD00003401
EINECS
247-429-1

Chemical Properties

Formula
AgSbF6
Formula Weight
343.41
Form
Powder/Lump
Storage & Sensitivity
Hygroscopic. Light Sensitive. Ambient temperatures.
Solubility
Soluble in water.

Applications

Silver hexafluoroantimonate is used as a catalyst for the preparation of a number of compounds. It acts as an acidic catalyst in epoxide opening reactions and sulfenylation reactions , controlled initiator in polymerization reactions, and as an activator of catalyst in certain organic reactions.

Notes

Stable at room temperature. Hygroscopic, light sensitive, very corrosive, and incompatible with strong oxidizing agents.

Literature References

Li, J.; Liu, Y.; Li, C.; Jia, X. Silver Hexafluoroantimonate-Catalyzed Three-Component [2+2+1]?Cycloadditions of Allenoates, Dual Activated Olefins, and Isocyanides. Advanced Synthesis & Catalysis 2011, 353 (6), 913-917.

Briones, J. F.; Davies, H. M. L. Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers. J. Am. Chem. Soc. 2013, 135 (36), 13314-13317.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H332-H335

Harmful if swallowed. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P301+P312-P304+P340-P312-P330-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.29
TSCA
Yes

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