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Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. In medical filed, it is used as topical caries in aqueous form in dentistry. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. In addition to this, it is used as a desulfuration-fluorination reagent on thiourea derived substrates.
Braganza, J. F.; Bernier, L.; Botrous, I.; Collins, M. R.; Li, B.; McAlpine, I.; Ninkovic, S.; Ren, S.; Sach, N.; Tran-Dube, M.; Zeng, Q.; Zheng, B. Improved cyclization conditions to prepare 6-substituted pyrazolo[1,5-a]pyridines and pyrazolo[1,5-a]pyrazines using catalytic Ag(I) and Au(III) salts. Tetrahedron Lett. 2015, 56 (42), 5757-5760.
Kremlev, M. M.; Mushta, A. I.; Tyrra, W.; Yagupolskii, Y. L.; Naumann, D.; Schäfer, M. Approaches to prepare perfluoroalkyl and pentafluorophenyl copper couples for cross-coupling reactions with organohalogen compounds. Dalton Trans. 2015, 44 (45), 19693-19699.
Hazard Statements: H314-H335
Causes severe skin burns and eye damage. May cause respiratory irritation.
Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant