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11614 Zinc perchlorate hexahydrate, Reagent Grade

CAS Number
10025-64-6
Synonyms

Stock No. Size Price ($) Quantity Availability
11614-22 100g 26.00
11614-36 500g 85.30
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Zinc perchlorate hexahydrate, Reagent Grade

MDL
MFCD00150370
EINECS
237-122-0

Chemical Properties

Formula
Cl2O8Zn•6H2O
Formula Weight
372.37 (264.28anhy)
Form
Crystalline
Melting point
106°
Density
2.25
Refractive Index
1.50
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water, alcohol

Applications

Zinc perchlorate hexahydrate, efficiently catalyses the esterification between nearly equimolar amounts of carboxylic acids and alcoholsZinc perchlorate hexahydrate [Zn (ClO4) 2· 6H2O] was found to be a highly efficient catalyst for acylation of electron deficient phenols, sterically hindered alcohols and electron deficient and sterically hindered amines. Zinc (II) perchlorate hexahydrate has been found to be a new and efficient catalyst for conjugate addition of thiols to α, β-unsaturated ketones under solvent-free conditions at room temperature.

Notes

Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong reducing agents, flammable substances, organic materials, metal powders. Desiccate at room temperature. Keep away from combustible material.

Literature References

G. Bartoli,; J. Boeglin,; M. Bosco,; M. Locatelli,; M. Massaccesi,; P. Melchiorre,; L. Sambri.Highly Efficient Solvent-Free Condensation of Carboxylic Acids with Alcohols Catalysed by Zinc Perchlorate Hexahydrate, Zn(ClO4)2.6H2O. Advanced Synthesis & Catalysis. 2005, 347 (1) , 33-38.

Shivani,; Rajesh Gulhane,; Asit K. Chakraborti. Zinc perchlorate hexahydrate [Zn(ClO4)2·6H2O] as acylation catalyst for poor nucleophilic phenols, alcohols and amines: Scope and limitations Journal of Molecular Catalysis A: Chemical. 2007, 264 (1-2), 208-213.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,10148
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2829.90
TSCA
Yes
RTECS
SD0525000

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