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13446-19-0 - Magnesium perchlorate hexahydrate, 99% (metals basis) - 11635 - Alfa Aesar

11635 Magnesium perchlorate hexahydrate, 99% (metals basis)

CAS Number
13446-19-0
Synonyms

Size Price ($) Quantity Availability
250g 34.00
1kg 126.00
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Magnesium perchlorate hexahydrate, 99% (metals basis)

MDL
MFCD00149778
EINECS
233-108-3

Chemical Properties

Formula
Mg(ClO4)2•6H2O
Formula Weight
331.33 (223.23anhy)
Form
Crystalline
Melting point
185-190°
Sensitivity
Hygroscopic
Solubility
Insoluble in water.

Applications

Commercially available magnesium perchlorate is reported as an extremely efficient catalyst for the synthesis of α-aminophosphonates. Magnesium perchlorate has been found to be an efficient catalyst for the synthesis of imines and phenylhydrazones by the reaction of carbonyl compounds with amines and phenylhydrazine in high yields at room temperatures and in short times.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, reducing agents, flammable substances, metal powders.

Literature References

Roderick J. Acheson,; Patrick W. M. Jacobs.The thermal decomposition of magnesium perchlorate and of ammonium perchlorate and magnesium perchlorate mixtures . J. Phys. Chem., 1970, 74 (2), 281-288.

Asit K. Chakraborti,; Srikant Bhagat,; Santosh Rudrawar. Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones Tetrahedron Letters. 2004, 45 (41) ,7641-7644.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5678
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2829.90
TSCA
Yes

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