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7791-03-9 - Lithium perchlorate, anhydrous, ACS, 95.0% min - 11639 - Alfa Aesar

11639 Lithium perchlorate, anhydrous, ACS, 95.0% min

CAS Number
7791-03-9
Synonyms

Size Price ($) Quantity Availability
10g 19.00
100g 51.40
500g 144.00
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Lithium perchlorate, anhydrous, ACS, 95.0% min

MDL
MFCD00011079
EINECS
232-237-2

Chemical Properties

Formula
ClLiO4
Formula Weight
106.40
Form
Crystalline
Melting point
236°
Boiling Point
400° dec.
Density
2.43
Sensitivity
Hygroscopic
Solubility
Soluble in water, alcohol and ethyl acetate.

Grade Specifications

Maximum level of impurities: Insoluble matter 0.005%, pH of a 5% solution 6.0-7.5 at 25°, Cl 0.003%, SO<sub>4</sub> 0.001%, Heavy Metals (ICP-OES) 5ppm, Fe 5ppm

Applications

Lithium perchlorate is used as an oxygen source for chemical oxygen generators, as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte, and act as chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

Notes

Hygroscopic in nature. Keep away from heat and sources of ignition. Keep the container tightly closed in a dry and well-ventilated place.

Literature References

Karim, S. R. A.; Sim, L. H.; Chan, C. H.; Ramli, h. On Thermal and Spectroscopic Studies of Poly(ethylene oxide)/Poly(methyl methacrylate) Blends with Lithium Perchlorate. Macromol. Symp. 2015, 354 (1), 374-383.

świergiel, J.; PŁowaś, I.; Jadżyn, J. Charge Relaxation and Stokes-Einstein Relation in Diluted Electrolyte Solution of Propylene Carbonate and Lithium Perchlorate. Ind. Eng. Chem. Res. 2015, 54 (7), 2108-2113.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5539
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2829.90
TSCA
Yes

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