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11639 Lithium perchlorate, anhydrous, ACS, 95.0% min

CAS Number
7791-03-9
Synonyms

Stock No. Size Price ($) Quantity Availability
11639-09 10g 20.40
11639-22 100g 54.00
11639-36 500g 153.00
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Lithium perchlorate, anhydrous, ACS, 95.0% min

MDL
MFCD00011079
EINECS
232-237-2

Chemical Properties

Formula
ClLiO4
Formula Weight
106.40
Form
Crystalline
Melting point
236°
Boiling Point
400° dec.
Density
2.43
Storage & Sensitivity
Hygroscopic. Store under Argon. Ambient temperatures.
Solubility
Soluble in water, alcohol and ethyl acetate.

Applications

Lithium perchlorate is used as an oxygen source for chemical oxygen generators, as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte, and act as chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

Notes

Hygroscopic in nature. Keep away from heat and sources of ignition. Keep the container tightly closed in a dry and well-ventilated place.

Literature References

Karim, S. R. A.; Sim, L. H.; Chan, C. H.; Ramli, h. On Thermal and Spectroscopic Studies of Poly(ethylene oxide)/Poly(methyl methacrylate) Blends with Lithium Perchlorate. Macromol. Symp. 2015, 354 (1), 374-383.

świergiel, J.; PŁowaś, I.; Jadżyn, J. Charge Relaxation and Stokes-Einstein Relation in Diluted Electrolyte Solution of Propylene Carbonate and Lithium Perchlorate. Ind. Eng. Chem. Res. 2015, 54 (7), 2108-2113.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H315-H319-H335

May cause fire or explosion; strong oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P261-P264b-P271-P280-P283-P302+P352-P304+P340-P305+P351+P338-P306+P360-P312-P332+P313-P337+P313-P363-P370+P378q-P371+P380+P375-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear fire/flame resistant/retardant clothing. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5539
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2829.90
TSCA
Yes

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