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563-63-3 - Silver acetate, anhydrous, 99% - 11660 - Alfa Aesar

11660 Silver acetate, anhydrous, 99%

CAS Number
563-63-3
Synonyms

Size Price ($) Quantity Availability
25g 86.73
100g 277.07
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Silver acetate, anhydrous, 99%

MDL
MFCD00012446
EINECS
209-254-9

Chemical Properties

Formula
C2H3AgO2
Formula Weight
166.92
Form
Crystalline
Melting point
dec.
Density
3.26
Sensitivity
Light Sensitive
Solubility
Soluble in dilute HNO{3}. Solubility in water increases with temperature.

Applications

It finds use in gum, spray, and lozenges to prevent smokers from smoking. When mixed with smoke, silver acetate creates an unpleasant metallic taste in the smoker's mouth, thus prevent them from smoking. It is a reagent in the laboratory as a source of silver ions lacking an oxidizing anion. It is a reagent for direct ortho-arylation, and for conversion of organohalogen compounds into alcohols. Woodward cis-hydroxylation reaction employs silver acetate and iodine for selective conversin of alkenes into cis-diols. Silver acetate is the more preferred reagent for facile carbonylation of primary and secondary amines. It is also employed in the preparation of highly reflective, conductive silvered polymer films.

Notes

It is a crystalline solid; photosensitive in nature.

Literature References

Abbiati, F.; Rossi, E. Silver and Gold Catalyzed Multicomponent Reactions. Beilstein J. Org. Chem. 2014, 10, 481-513.

Jeanmonod, P.; Laschke, M. W.; Gola, N.; von Heesen, M.; Glanemann, M.; Dold, S.; Menger, M. D.; Moussavian, M. R. Silver Acetate Coating Promotes Early Vascularization of Dacron Vascular Grafts without Inducing Host Tissue Inflammation. J. Vasc. Surg. 2013, 58 (6), 1637-1643.

GHS Hazard and Precautionary Statements

Hazard Statements: H400-H410-H315

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Causes skin irritation.

Precautionary Statements: P273-P280-P264-P362-P321-P332+P313-P302+P352-P391-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. Collect spillage. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8505
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2843.29
TSCA
Yes
RTECS
AJ4100000

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