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7440-18-8 - Ruthenium, 10% on activated carbon powder, reduced - 11757 - Alfa Aesar

11757 Ruthenium, 10% on activated carbon powder, reduced

CAS Number
7440-18-8
Synonyms

Size Price ($) Quantity Availability
5g 46.80
25g 167.00
100g 538.00
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Ruthenium, 10% on activated carbon powder, reduced

MDL
MFCD00011207
EINECS
231-127-1

Chemical Properties

Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

Ruthenium, 10% on activated carbon powder is used in hydrogenation of aromatic ring systems, particularly the hindered systems. It finds wide use for the reduction of aliphatic carbonyl compounds and carboxylic acids to alcohols, hydrogenation of anilines to cyclohexylamines, synthesis of ammonia, depolymerization of carbohydrates, Fischer-Tropsch synthesis, and hydrogenation of glucose to produce sorbitol.

Notes

Incompatible with oxidizing agents and halogens.

Literature References

Barfi, B.; Rajabi, M.; Zadeh, M. M.; Ghaedi, M.; Salavati-Niasari, M.; Sahraei, R. Extraction of ultra-traces of lead, chromium and copper using ruthenium nanoparticles loaded on activated carbon and modified with N, N-bis-(α-methylsalicylidene)-2, 2-dimethylpropane-1, 3-diamine. Microchim. Acta 2015, 182 (5-6), 1187-1196.

Mazaheri, H.; Ghaedi, M.; Hajati, S.; Dashtian, K.; Purkait, M. K. Simultaneous removal of methylene blue and Pb2+ ions using ruthenium nanoparticle-loaded activated carbon: response surface methodology. RSC Adv. 2015, 5 (101), 83427-83435.

Li, Y.; Pan, C.; Han, W.; Chai, H.; Liu, H. An efficient route for the preparation of activated carbon supported ruthenium catalysts with high performance for ammonia synthesis. Catal. Today 2011, 174 (1), 97-105.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H252

Flammable solid. Self-heating in large quantities; may catch fire.

Precautionary Statements: P210-P280-P235+P410-P240-P241-P370+P378a-P420-P407

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Keep cool. Protect from sunlight. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray. Store away from other materials. Maintain air gap between stacks/pallets.

Other References

Hazard Class
4.2
Packing Group
III
Harmonized Tariff Code
3815.12
TSCA
Yes

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