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12036-10-1 - Ruthenium(IV) oxide, anhydrous, Premion®, 99.95% (metals basis), Ru 75.2% min - Ruthenium dioxide - 11804 - Alfa Aesar

11804 Ruthenium(IV) oxide, anhydrous, Premion®, 99.95% (metals basis), Ru 75.2% min

CAS Number
12036-10-1
Synonyms
Ruthenium dioxide

Size Price ($) Quantity Availability
0.5g 31.20
2g 139.95
10g 633.42
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Ruthenium(IV) oxide, anhydrous, Premion®, 99.95% (metals basis), Ru 75.2% min

MDL
MFCD00011210
EINECS
234-840-6

Chemical Properties

Formula
O2Ru
Formula Weight
133.07
Form
Powder
Melting point
1200° subl.
Density
6.97
Sensitivity
Hygroscopic
Solubility
Insoluble in water, and acids. Soluble in fused alkali.

Applications

The most often used oxygen catalyst is ruthenium(IV) oxide. It is applied as an electrochemical super capacitor material, and it has high capacity to store charge. RuO<sub>2</sub> is used as catalyst in the Deacon process which produces chlorine through the oxidation of hydrogen chloride. Owing to the high charge transfer capability, it is used as active material in super capacitors. The dispersion property of RuO2 is used to increase the capacitance of nanocomposite electrode materials for supercapacitors. RuO2 is extensively used for the coating of titanium anodes, and as a catalyst and doping agent, for use in the removal of hydrogen sulfide from oil refineries.

Notes

Incompatible with oxidizers, acids, aqua regia, organic solvents.

Literature References

Hu, M. L.; Safarifard. V.; Morsali, A.; Shao, T. L.; Li, X. Facile fabrication of ruthenium(IV) oxide nanostructures by thermal decomposition of two new organoruthenium(II) complexes. Inorg. Chem. Commun. 2013, 37, 189-192.

Mani, R.; Fischer, M.; Joy, E.; Gopalakrishnan, J.; Jansen, M. Ruthenium(IV) pyrochlore oxides: Realization of novel electronic properties through substitution at A- and B-sites. Solid State Sci. 2009, 11 (1), 189-194.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H303

May cause fire or explosion; strong oxidizer. May be harmful if swallowed.

Precautionary Statements: P221-P283-P210-P220-P280-P306+P360-P371+P380+P375-P312-P370+P378a-P501a

Take any precaution to avoid mixing with combustibles. Wear fire/flame resistant/retardant clothing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use for extinction: CO2, powder or water spray. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
VM2654000

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