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11816 Rhodium(III) bromide hydrate

CAS Number
123333-87-9
Synonyms

Stock No. Size Price ($) Quantity Availability
11816-03 1g 300.00
11816-06 5g 1344.00
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Rhodium(III) bromide hydrate

MDL
MFCD00149837
EINECS
239-687-9

Chemical Properties

Formula
RhBr3•xH2O
Formula Weight
342.62(anhy)
Form
Crystalline
Storage & Sensitivity
Hygroscopic. Ambient temperatures.

Applications

Rhodium(III) bromide hydrate is used to prepare coordination complex, trans-dibromotetrakis(pyridine)rhodium(III) bromide hexahydrate. It is also involved in the preparation of rhodium nanoparticles.

Notes

Hygroscopic. Moisture sensitive. Incompatible with water, acid and oxidizing agents.

Literature References

Arachchige, S. M.; Brown, J.; Brewer, K. J. Photochemical hydrogen production from water using the new photocatalyst [{(bpy)2Ru(dpp)}2RhBr2](PF6)5. J. Photochem. Photobiol., A 2008, 197 (1), 13-17.

Zhang, Y.; Grass, M. E.; Huang, W.; Somorjai, G. A. Seedless Polyol Synthesis and CO Oxidation Activity of Monodisperse (111)-and (100)-Oriented Rhodium Nanocrystals in Sub-10 nm Sizes. Langmuir 2010, 26 (21), 16463-16468.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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