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Hafnium chloride tetrahydrofuran complex is an efficient catalyst for the Diels-Alder cycloadditions, Ziegler-Natta polymerization of alkenes. It is used as control rods in nuclear reactors and in manufacture of light bulb filaments.
Mukhopadhyay, A. B.; Musgrave, C. B.; Fdez Sanz, J. Atomic layer deposition of hafnium oxide from hafnium chloride and water. J. Am. Chem. Soc. 2008, 130 (36), 11996-12006.
Ikeda, K.; Inoue, K.; Kanematsu, S.; Horiuchi, Y.; Park, P. Enhanced effects of nonisotopic hafnium chloride in methanol as a substitute for uranyl acetate in TEM contrast of ultrastructure of fungal and plant cells. Microsc. Res. Tech. 2011, 74 (9), 825-830.
Hazard Statements: H290-H314-H318
May be corrosive to metals. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.