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26042-63-7 - Silver hexafluorophosphate, 98% - 11873 - Alfa Aesar

11873 Silver hexafluorophosphate, 98%

CAS Number
26042-63-7
Synonyms

Size Price ($) Quantity Availability
1g 35.95
5g 106.80
25g 337.50
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Silver hexafluorophosphate, 98%

MDL
MFCD00003415
EINECS
247-428-6

Chemical Properties

Formula
AgF6P
Formula Weight
252.83
Form
Powder
Melting point
102° dec.
Sensitivity
Light Sensitive
Solubility
Soluble in organic solvents such as benzene, toluene, and acetonitrile.

Applications

It is commonly used as an oxidant forming silver metal. It is often used as a reagent in inorganic and organometallic chemistry. It is used in the preparation of engineering novel materials as well as in preparation of supra molecular Ag(I) complexes. It is used in the development of new catalysts, replacing halide ligands with the weakly coordinating hexafluorophosphate anion.

Notes

Stable under room temperatures and pressures. Moisture sensitive, hygroscopic, and may discolor on exposure to light. Incompatible with strong oxidizing agents and strong acids.

Literature References

Galan, R. F.; Manzano, B. R.; Otero, A.; Lanfranchi, M.; Pellinghelli, M. A. 19F and 31P NMR evidence for silver hexafluorophosphate hydrolysis in solution. New palladium difluorophosphate complexes and x-ray structure determination of [Pd(.eta.3-2-Me-C3H4)(PO2F2)(PCy3)]Inorg. Chem. 1994, 33 (10), 2309-2312.

Hirsch, K. A.; Wilson, S. R.; Moore, J. S. Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:? Structural Diversity through Changes in Ligand Conformation and Counter ion. Inorg. Chem. 1997, 36 (14), 2960-2968.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H400

Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic to aquatic life.

Precautionary Statements: P273-P280-P303+P361+P353-P305+P351+P338-P310

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.29
TSCA
Yes

Recommended

  • 11414

    Silver nitrate, ACS, 99.9+% (metals basis)
  • 11538

    Silver hexafluoroantimonate, 99%
  • 12303

    Cobalt(II) chloride, anhydrous, 99.7% (metals basis)
  • 12457

    Copper(II) chloride, anhydrous, 98% min
  • 88722

    Silver trifluoromethanesulfonate, 98%

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