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11881 Palladium(II) iodide, 99.9% (metals basis), Pd 28% min

CAS Number
7790-38-7
Synonyms

Stock No. Size Price ($) Quantity Availability
11881-04 2g 134.00
11881-09 10g 607.00
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Palladium(II) iodide, 99.9% (metals basis), Pd 28% min

MDL
MFCD00011171
EINECS
232-203-7

Chemical Properties

Formula
PdI2
Formula Weight
360.23
Form
Powder
Melting point
350° dec.
Density
6.003
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ammonia, methyl acetate and potassium iodide. Slightly soluble in hydriodic acid and concentrated nitric acid. Insoluble in water, ethanol, diluted nitric acid, hydrochloric acid and diethyl ether.

Applications

Palladium(II) iodide is used in gravimetric analysis. It is involved in the synthesis of symmetrical and unsymmetrical ureas.

Notes

Incompatible with strong oxidizing agents and mineral acids.

Literature References

Queirolo, M.; Vezzani, A.; Mancuso, R.; Gabriele, B.; Costa, M.; Della Ca, N. Neutral vs anionic palladium iodide-catalyzed carbonylation of terminal arylacetylenes. J. Mol. Catal. A: Chem. 2015, 398, 115-126.

Mancuso, R.; Ziccarelli, I.; Armentano, D.; Marino, N.; Giofre, S. V.; Gabriele, B. Divergent Palladium Iodide Catalyzed Multicomponent Carbonylative Approaches to Functionalized Isoindolinone and Isobenzofuranimine Derivatives. J. Org. Chem. 2014, 79 (8), 3506-3518.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H334

Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements: P261-P264b-P280-P285-P302+P352-P304+P341-P305+P351+P338-P332+P313-P337+P313-P342+P311-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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