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10026-11-6 - Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis) - Zirconium tetrachloride - 12104 - Alfa Aesar

12104 Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

CAS Number
10026-11-6
Synonyms
Zirconium tetrachloride

Size Price ($) Quantity Availability
10g 24.80
100g 35.10
500g 118.00
2kg 337.00
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Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

MDL
MFCD00011306
EINECS
233-058-2

Chemical Properties

Formula
ZrCl4
Formula Weight
233.03
Form
Powder
Melting point
331° subl.
Density
2.803
Sensitivity
Moisture Sensitive
Solubility
Soluble in alcohol, ether, hydrochloric acid.

Applications

Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.

Notes

It is stable under room temperatures. Strongly hygroscopic and decomposes in water forming ZrOCl2 and HCl.

Literature References

Meshram, H. M.; Premalatha, K.; Rameshbabu, K.; Eeshwaraiah, B.; Yadav, J. S. Zirconium(IV) Chloride Catalyzed Cyclization of ortho-Allylphenols: Synthesis of 2-Methyl-2,3-dihydrobenzofurans. Synth. Commun. 2004, 34 (17), 3091-3097.

Smitha, G.; Chandrasekhar, S.; Sanjeeva Reddy, C. Applications of Zirconium(IV) Chloride in Organic Synthesis. Synthesis 2008, 6, 829-855.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H318

Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,10174
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
ZH7175000

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