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12169 Potassium hexachloroplatinate(IV), Pt 39.6%

CAS Number
16921-30-5
Synonyms

Stock No. Size Price ($) Quantity Availability
12169-01 0.25g 35.70
12169-03 1g 116.00
12169-06 5g 523.00
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Potassium hexachloroplatinate(IV), Pt 39.6%

MDL
MFCD00011389
EINECS
240-979-3

Chemical Properties

Formula
Cl6K2Pt
Formula Weight
486.01
Form
Crystalline powder
Melting point
250°dec.
Density
3.50
Refractive Index
^=1.825
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in hot water. Slightly soluble in cold water. Practically insoluble in alcoholSoluble in hot water. Slightly soluble in cold water. Insoluble in alcohol.

Applications

Potassium hexachloroplatinate(IV) is used for the determination of potassium by gravimetric analysis. It is also used to prepare potassium tetrchloroplatinate by reduction using hydrazine dihydrochloride. Further, it is used in photography.

Notes

Incompatible with acids, interhalogen compounds and strong oxidizing agents.

Literature References

Soni, S. K.; Sarkar, S.; Selvakannan, P. R.; Sarkar, D.; Bhargava, S. K. Intrinsic therapeutic and biocatalytic roles of ionic liquid mediated self-assembled platinum-phytase nanospheres. RSC Adv. 2015, 5 (77), 62871-62881.

Channon, R. B.; Joseph, M. B.; Bitziou, E.; Bristow, A. W.; Ray, A. D.; Macpherson, J. V. Electrochemical Flow Injection Analysis of Hydrazine in an Excess of an Active Pharmaceutical Ingredient: Achieving Pharmaceutical Detection Limits Electrochemically. Anal. Chem. 2015, 87 (19), 10064-10071.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H301-H317-H318-H334-H335-H373

May be corrosive to metals. Toxic if swallowed. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P234-P260-P264b-P270-P271-P272-P280-P285-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P314-P330-P333+P313-P342+P311-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7636
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
TP1650000

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