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34513-98-9 - Ruthenium(III) nitrosylnitrate, Ru 31.3% min - 12175 - Alfa Aesar

12175 Ruthenium(III) nitrosylnitrate, Ru 31.3% min

CAS Number
34513-98-9
Synonyms

Size Price ($) Quantity Availability
1g 73.20
5g 261.00
25g 1180.00
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Ruthenium(III) nitrosylnitrate, Ru 31.3% min

MDL
MFCD00016313
EINECS
252-068-8

Chemical Properties

Formula
N4O10Ru
Formula Weight
317.09
Form
Crystalline
Melting point
dec.
Solubility
Miscible with cold water.

Applications

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Notes

Incompatible with reducing agents, phosphorus, sulfur and organic matter.

Literature References

Zoehrer, H.; Mayr, F.; Vogel, F. Stability and Performance of Ruthenium Catalysts Based on Refractory Oxide Supports in Supercritical Water Conditions. Energy Fuels 2013, 27 (8), 4739-4747.

Rose, M. J.; Mascharak, P. K. Photoactive Ruthenium Nitrosyls: Effects of Light and Potential Application as NO Donors. Coord. Chem. Rev. 2008, 252 (18-20), 2093-2114.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H290-H314-H318

May intensify fire; oxidizer. May be corrosive to metals. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P221-P210v-P303+P361+P353-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes

Recommended

  • 10561

    Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), Rh 25.2% min
  • 10694

    Cobalt(II) nitrate hexahydrate, Puratronic®, 99.999% (metals basis)
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min
  • 11329

    Cerium(III) nitrate hexahydrate, REacton®, 99.5% (REO)
  • 11341

    Cobalt(II) nitrate hexahydrate, 97.7% min

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