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12222 Nickel(II) nitrate hexahydrate, tech., Ni 19.8% min

CAS Number
13478-00-7
Synonyms

Stock No. Size Price ($) Quantity Availability
12222-36 500g 39.60
12222-A3 2kg 78.00
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Nickel(II) nitrate hexahydrate, tech., Ni 19.8% min

MDL
MFCD00149805
EINECS
236-068-5

Chemical Properties

Formula
N2NiO6•6H2O
Formula Weight
290.80 (182.70anhy)
Form
Flake
Melting point
56.7°
Boiling Point
137°
Density
2.05
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water, alcoholVery soluble in water. Soluble in ethanol.

Applications

Nickel plating, manufacturing of ceramic colorsNickel(II) nitrate hexahydrate is used as a precursor in the manufacturing of other nickel salts and supported nickel catalysts. It finds use as a catalyst in organic synthesis. Further it is used in electroplating and as a mordent in textile dyeing. It is a precursor for preparing nickel sulfide-reduced graphene oxide (RGO) composite powders with high initial capacities and good cycling performance. It can be employed in the preparation of nickel and nickel oxide nanocrystals impregnated O-MWCNTs (oxygen-functionalized multi-walled carbon nanotubes) with potential applications in semiconductor industries. It finds use in improving cycling stability ad rate capability of Li2MnO3.

Notes

As an oxidizer, it is incompatible with reducing agents.

Literature References

Lee, S. M.; Ko, Y. N.; Choi, S. H.; Kim, J. H.; Kang, Y. C. Capacitive properties of reduced graphene oxide microspheres with uniformly dispersed nickel sulfide nanocrystals prepared by spray pyrolysis. Electrochim. Acta 2015, 167, 287-293.

Klein, A.; Axmann, P.; Yada, C.; Wohlfahrt-Mehrens, M. Improving the cycling stability of Li2MnO3 by surface treatment. J. Power Sources 2015, 2, 302-307.

Wang, W. N.; Itoh, Y.; Lenggoro, I. W.; Okuyama, K. Nickel and Nickel oxide Nanoparticles Prepared from Nickel nitrate hexahydrate by a Low Pressure Spray Pyrolysis. Mat. Sci. Eng. B-Solid 2004, 111 (1), 69-76.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H302+H332-H315-H317-H318-H334-H335-H341-H350i-H360D-H372

May intensify fire; oxidizer. Harmful if swallowed. Harmful if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. May cause cancer by inhalation. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P220-P221-P260-P264b-P270-P271-P272-P280g-P281-P285-P301+P312-P302+P352-P304+P340-P305+P351+P338-P308+P313-P310-P330-P333+P313-P342+P311-P362-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation or rash occurs: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6513
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
QR7300000

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