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7782-61-8 - Iron(III) nitrate nonahydrate, 98+% (metals basis) - 12226 - Alfa Aesar

12226 Iron(III) nitrate nonahydrate, 98+% (metals basis)

CAS Number
7782-61-8
Synonyms

Size Price ($) Quantity Availability
100g 18.54
1kg 43.67
5kg 82.71
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Iron(III) nitrate nonahydrate, 98+% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Chemical Properties

Formula
FeN3O9•9H2O
Formula Weight
403.99 (241.86anhy)
Form
Crystalline, Contains excess HNO3
Melting point
47°
Boiling Point
125° dec.
Density
1.684
Sensitivity
Moisture Sensitive
Solubility
Soluble in water, alcohol and acetone.

Applications

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Notes

Keep away from materials like organic and powdered metals.

Literature References

Soni, P. A.; Gupta, P. K.; Maurya, C. K.; Halve, A. K.; Ganesan, K. Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation. Tetrahedron Lett. 2015, 56 (21), 2817-2819.

Jastrzebski, R.; Van den Berg, E. J.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Sustainable production of dimethyl adipate by non-heme iron(III) catalysed oxidative cleavage of catechol. Catal. Sci. Technol. 2015, 5, 2103-2109.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P221-P210-P220-P280-P305+P351+P338-P362-P321-P332+P313-P337+P313-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,4027
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2834.29
TSCA
Yes
RTECS
NO7175000

Recommended

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  • A18521

    Manganese(II) nitrate tetrahydrate, 98%
  • 11341

    Cobalt(II) nitrate hexahydrate, 97.7% min
  • 11565

    Chromium(III) nitrate nonahydrate, 98.5%
  • 12357

    Iron(III) chloride, anhydrous, 98%

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