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12231 Bismuth(III) nitrate pentahydrate, ACS, 98% min

CAS Number
10035-06-0
Synonyms

Stock No. Size Price ($) Quantity Availability
12231-30 250g 46.40
12231-A1 1kg 140.00
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Bismuth(III) nitrate pentahydrate, ACS, 98% min

MDL
MFCD00149157
EINECS
233-791-8

Chemical Properties

Formula
Bi(NO3)3•5H2O
Formula Weight
485.07 (394.99anhy)
Form
Crystalline
Melting point
30° dec.
Density
2.83
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in dilute HNO{3} acid solution. Decomposes in water to subnitrate. Soluble in dilute acetic acid, glycerol, acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.

Grade Specifications

Maximum level of impurities: Insoluble matter 0.005%, Cl 0.001%, SO4 0.005%, As 0.001%, Cu 0.002%, Fe 0.001%, Pb 0.002%, K 0.01%, Na 0.02%, Ag 0.001%

Applications

Luminous paints, preparation of bismuth saltsBismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Notes

Hygroscopic. Moisture sensitive. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, powdered metals and organic materials.

Literature References

Zahedifar, M.; Sheibani, H. Rapid three-component synthesis of pyrimidine and pyrimidinone derivatives in the presence of Bi(NO3) 3· 5H2O as a mild and highly efficient catalyst. Res. Chem. Intermed. 2015, 41 (1), 105-111.

Pei, C. C.; Leung, W. W. F. Photocatalytic oxidation of nitrogen monoxide and o-xylene by TiO2/ZnO/Bi2O3 nanofibers: Optimization, kinetic modeling and mechanisms. Appl. Catal., B 2015, 174, 515-525.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319-H335-H373

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P220-P221-P261-P262-P264b-P271-P280i-P281-P302+P352-P304+P340-P305+P351+P338-P308+P313-P332+P313-P337+P313-P362-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1271
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2834.29
TSCA
Yes

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