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12274 Mercury(II) chloride, ACS, 99.5% min

CAS Number
7487-94-7
Synonyms

Stock No. Size Price ($) Quantity Availability
12274-14 25g 36.60
12274-22 100g 104.00
12274-36 500g 467.00
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Mercury(II) chloride, ACS, 99.5% min

MDL
MFCD00011041
EINECS
231-299-8

Chemical Properties

Formula
Cl2Hg
Formula Weight
271.50
Form
Powder
Melting point
280-282°
Boiling Point
302°
Density
5.4
Refractive Index
1.859
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in boiling water (solubility in cold water is increased by HCl or alkali chlorides), alcohol, glycerol, methanol, acetone, and ethyl acetateSoluble in water, alcohol, acetone and ethyl acetate. Slightly soluble in benzene, carbon disulfide and pyridine.

Grade Specifications

Maximum level of impurities: Residue after reduction 0.02%, Solution in ethyl ether P.T., Fe 0.002%

Applications

Mercury(II) chloride is used as a catalyst in making plastics, depolarizer in batteries and as a reagent in organic synthesis and analytical chemistry. It is also used to prepare an amalgam with metals such as aluminum, which finds application as reducing agent in organic synthesis. It also finds application in photography as a photographic intensifier. Further, it serves as a preservative and used in the treatment of syphilis. It is also used to remove dithiane groups bonded to a carbonyl in an umpolung reaction.

Notes

Light and moisture sensitive. Incompatible with strong oxidizing agents and strong bases.

Literature References

Rajasekar, M.; Muthu, K.; Prasad, A. A.; Meenakshisundaram, S. P. Growth, hyperpolarizability, characterization and theoretical studies of NLO active tris (allylthiourea) mercury(II) chloride. J. Mol. Struct. 2015, 1085 147-154.

Huang, Y.; Du, J. R.; Zhang, Y.; Lawless, D.; Feng, X. Removal of mercury(II) from wastewater by polyvinylamine-enhanced ultrafiltration. Sep. Purif. Technol. 2015, 154, 1-10.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H314-H335-H341-H361f-H372

Fatal if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertility. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P260-P262-P264b-P270-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5876
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2852.10
TSCA
Yes
RTECS
OV9100000

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