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12137-21-2 - Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min - Adams' Catalyst - 12278 - Alfa Aesar

12278 Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min

CAS Number
12137-21-2
Synonyms
Adams' Catalyst

Size Price ($) Quantity Availability
1g 186.43
5g 780.92
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Platinum(IV) oxide monohydrate, Adams Catalyst, Pt 75% min

MDL
MFCD00066964
EINECS
215-223-0

Chemical Properties

Formula
O2Pt•H2O
Formula Weight
245.10 (227.09anhy)
Form
Powder, S.A. >85m2/g
Melting point
450°
Solubility
Insoluble in water, acid, aqua regiaSoluble in water and caustic potash solution. Insoluble in alcohol, acid and aqua regia.

Applications

Hydrogenation catalyst. Suitable for the reduction of double and triple bonds, aromatics, carbonyls, nitriles, and nitro groupsPlatinum(IV) oxide monohydrate is used as a catalyst in hydrogenation, hydrogenolysis, dehydrogenation, and oxidation reactions in organic synthesis. It also finds application in ceramic industry, inorganic chemistry and in chemical synthesis. It is utilized for the selective reduction of alkenes without reducing nitro group.

Notes

Electrochemically prepared for catalyst useIncompatible with reducing agents, organic materials and metal powders.

Literature References

Zeininger, L.; Klaumünzer, M.; Peukert, W.; Hirsch, A. Surface Modification of ZnO Nanorods with Hamilton Receptors. Int. J. Mol. Sci. 2015, 16 (4), 8186-8200.

Andersen, S. M.; Bollmark, M.; Berg, R.; Fredriksson, C.; Karlsson, S.; Liljeholm, C.; So?rensen, H. A Scalable Route to 5-Substituted 3-Isoxazolol Fibrinolysis Inhibitor AZD6564. Org. Process Res. Dev. 2014, 18 (8), 952-959.

GHS Hazard and Precautionary Statements

Hazard Statements: H272

May intensify fire; oxidizer.

Precautionary Statements: P221-P210-P220-P280-P370+P378a-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7527
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
TP2506020

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