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13283-01-7 - Tungsten(VI) chloride, 99% - 12337 - Alfa Aesar

12337 Tungsten(VI) chloride, 99%

CAS Number
13283-01-7
Synonyms

Size Price ($) Quantity Availability
5g 29.97
10g 44.46
50g 151.20
250g 511.20
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Tungsten(VI) chloride, 99%

MDL
MFCD00011463
EINECS
236-293-9

Chemical Properties

Formula
WCl6
Formula Weight
396.57
Form
Powder
Melting point
275°
Boiling Point
346°
Density
3.52
Sensitivity
Moisture Sensitive
Solubility
Soluble in carbon disulfide, carbon tetrachloride and phosphorus oxychloride.

Applications

It is a precursor for many tungsten compounds. It is used in tungsten plating, purification of tungsten, and olefin polymerization. It is also used as petroleum catalyst, and in intelligent glass. It can be used for deoxygenation of epoxides and as a reagent in organic synthesis.

Notes

Oxidized in the air when heating, and transformed into tungsten oxychloride or tungsten oxide. Hydrolysis occurs with water. Protect from humidity and moisture. Store in cool, dry conditions in well sealed containers.

Literature References

Ren, Y.; Gao, Y.; Zhao, G. Facile single-step fabrications of electrochromic WO3 micro-patterned films using the novel photosensitive sol-gel method. Ceram. Inter. 2015, 41 (1), 403-408.

Zhang, J.; Wang, Q.; Wang, L.; Li, X.; Huang, W. Layer-controllable WS2-reduced graphene oxide hybrid nanosheets with high electrocatalytic activity for hydrogen evolution. Nanoscale 2015, 7, 10391-10397.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
YO7710000

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