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1309-60-0 - Lead(IV) oxide, ACS, 97.0% min - Lead dioxide - Lead peroxide - 12483 - Alfa Aesar

12483 Lead(IV) oxide, ACS, 97.0% min

CAS Number
1309-60-0
Synonyms
Lead dioxide
Lead peroxide

Size Price ($) Quantity Availability
100g 50.35
500g 128.75
2kg 420.25
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Lead(IV) oxide, ACS, 97.0% min

MDL
MFCD00011165
EINECS
215-174-5

Chemical Properties

Formula
PbO2
Formula Weight
239.19
Form
Powder
Melting point
290° dec.
Density
9.38
Solubility
Insoluble in water and alcohol. Soluble in acetic acid.

Grade Specifications

Maximum level of impurities: Acid-insoluble matter 0.2%, Carbon compounds (as C) 0.04%, Cl 0.002%, NO<sub>3</sub> 0.02%, SO<sub>4</sub> 0.05%, Mn 5ppm, Ca 0.02%, Cu 0.05%, K 0.05%, Na 0.1%

Applications

It finds applications as an electrode in lead acid batteries, as anode in electroplating copper and zinc in sulfate solution, production of glyoxylic acid, manufacturing of pigments and dyes, high voltage lightening arrestors, and as an analytical lab reagent. Lead dioxide is a potent oxidizing agent which is employed in the manufacture of matches, pyrotechnics and other chemicals. It can be used in the curing of sulfide-based polymers. It oxidizes Mn(II) into Mn(VII), and Cr(III) into Cr(VI).

Notes

It is a strong oxidant. Lead oxide should be kept away from strong oxidizing agents, strong reducing agents and powdered metals.

Literature References

Li, C. H.; Sengodu, P.; Wang, D. Y.; Kuo, T. R.; Chen, C. C. Highly stable cycling of a lead oxide/copper nanocomposite as an anode material in lithium ion batteries. RSC Adv. 2015, 5 50245-50252.

Li, L.; Zhu, X.; Yang, D.; Gao, L.; Liu, J.; VasantKumar, R.; Yang, J. Preparation and characterization of nano-structured lead oxide from spent lead acid battery paste. J. Hazard. Mater. 2012, 203-204 274-282.

GHS Hazard and Precautionary Statements

Hazard Statements: H360-H373-H272-H400-H410-H302-H332

May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. May intensify fire; oxidizer. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Harmful if inhaled.

Precautionary Statements: P221-P210-P260-P201-P220-P261-P273-P280-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5407
Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2824.90
TSCA
Yes

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