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14024-18-1 - Iron(III) 2,4-pentanedionate - Iron(III) acetylacetonate - Tris(acetylacetonato)iron(III) - 12534 - Alfa Aesar

12534 Iron(III) 2,4-pentanedionate

CAS Number
14024-18-1
Synonyms
Iron(III) acetylacetonate
Tris(acetylacetonato)iron(III)

Size Price ($) Quantity Availability
100g 47.28
500g 160.68
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Iron(III) 2,4-pentanedionate

MDL
MFCD00000020
EINECS
237-853-5

Chemical Properties

Formula
C15H21FeO6
Formula Weight
353.17
Form
Powder
Melting point
ca 183° dec.
Solubility
Soluble in toluene.

Applications

Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe<sub>2</sub>O<sub>4 </sub films and magnetic property measurements of these films. It catalyzes the dimerization of isoprene to a mixture of 1,5-dimethyl-1,5-cyclooctadiene and 2,5-dimethyl-1,5-cyclooctadiene, ring-opening polymerization of 1,3-benzoxazine and catalyze the reaction of N-sulfonyl oxaziridines with olefins to form 1,3-oxazolidine products.

Notes

Incompatible with strong bases and strong oxidizing agents.

Literature References

Liu, F.; Dong, Y.; Yang, W.; Yu, J.; Xu, Z.; Hou, Y. Exchange-Coupled fct-FePd/alpha-Fe Nanocomposite Magnets Converted from Pd/Fe3O4 Core/Shell Nanoparticles. Chem. Eur. J. 2014, 20 (46), 15197-15202.

Leu, C. C.; Lin, T. J.; Chen, S. Y.; Hu, C. T. Effects of Bismuth Oxide Buffer Layer on BiFeO3 Thin Film. J. Am. Ceram. Soc. 2015, 98 (3), 724-731.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H319

Harmful if swallowed. Causes serious eye irritation.

Precautionary Statements: P280-P264-P270-P305+P351+P338-P301+P312-P337+P313-P330-P501a

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4157960
Harmonized Tariff Code
2914.19
TSCA
Yes
RTECS
NO8960000

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